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Nuclei


Contents

Binding Energy
Origin of Elements
The Liquid-Drop and The Shell Models
Nuclear Decay
Fission
Fusion
Effects of Nuclear Explosions
References
Index

Binding Energy

Binding Energy Proton-Neutron Ratio A nucleus is specified by its number of protons Z, number of neutrons N, and the mass number A = Z+N. The nucleons (protons and neutrons) in a nucleus are bound together -- their total energy is less than the total energy of the separated particles. The binding energy is the amount of energy given up when the nucleus is formed. Plotting the binding energy per nucleon versus the mass number A (Figure 14-01) shows that starting from Hydrogen, nuclei become more

Figure 14-01 Nuclear Binding Energy
[view large image]

Figure 14-02 Proton/Neutron & Decay [view large image]

stable as there are more protons and neutrons, until Iron. After that, the trend reverses.
Figure 14-02 shows the distribution of the stable nuclei. As the mass numbers become higher, the ratio of neutrons to protons in the nucleus becomes larger. There are no stable nuclei with a mass number higher than 83 or a neutron number higher than 126. This limit is represented by the element Bismuth (see Figure 13-01b). Although it is not obvious from Figure 14-02 (due to its lack of detail) stability is favored by even numbers of protons and even numbers of neutrons. 168 of the stable nuclei are even-even while only 4 of the stable nuclei are odd-odd. Notice how the stability band pulls away from the P=N line. Figure 14-02 also shows all the trends of decay. There are some exceptions to the trends but generally a nucleus will decay following the trends (in multiple steps) until it becomes stable. This process is called a radioactive series. For example, the series for 92U238 will go through 8 alpha emissions and 6 beta emissions before becoming the stable nucleus 82Pb206.

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Origin of Elements

Origin of Elements Light elements (mainly hydrogen, helium and trace of deuterium, lithium) were generated in the first few minutes of the Big Bang, which was not able to produce more complex elements as the universe rapidly cooling off. Since then hydrogen and helium contribute by mass of respectively 70 and 28 per cent of all baryonic matter in the universe. Most of the remaining 2% of the elements up to iron and nickel are made in the interior of the stars. The resulting elements are thrust into space by booming stellar winds or when a star explodes as a supernova. Carbon, nitrogen and oxygen are the most abundant heavy elements. Oxygen is created by supernovae, while carbon is created in low-mass stars (red giants, planetary nebulae) and nitrogen is by a mixture of the above.

Figure 14-03 Element Abundance [view large

image]

The rest of the heavy elements come from a poorly understood process, which requires the presence of a staggering numbers of neutrons. It is thought that such event may occur in the collision of neutron stars or from supernova explosions that form neutron stars. There are 92 elements known to occur naturally on Earth; 83 of these are stable, and the others are radioactive. More than 20 elements with atomic numbers greater than 92, have been created artificially in particle accelerators. All are extremely unstable and decay rapidly into lighter elements. The "local galactic" abundance diagram of Figure 14-03 indicates the elements from hydrogen to beryllium are generated by BB (Big Bang); heavier elements up to nickel are produced by nuclear burning inside stars; the other heavy elements come from a neutron capturing process with the neutron subsequently decays to proton. Nuclear statistical equilibrium is referred to the state in which forward and reverse nuclear reactions balance.

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The Liquid-Drop and The Shell Models

Liquid Drop Model Nuclear Decay The liquid-drop model assumes that the constituents of the nucleus interact only with their nearest neighbors, and the density is constant inside the nucleus, like the molecules in the liquid. Using this analogy, a semiempirical formula has been developed to describe the binding energy as a function of the mass number A (shown by the solid curve in Figure 14-01). The result is not particularly accurate for the lower value of A. The expression is useful in discussing stability, radioactivity, and the fluctuations from the average behavior due to shell effects. The top diagram in Figure 14-04a shows two vibrational energy levels, which split into finer structures due to rotation.

Figure 14-04a Liquid Drop Model [view large image]

Figure 14-04b Fission [view large image]

Figure 14-04b shows the deformation of the liquid drop, which eventually separates into two pieces (caused by the electrostatic repulsion of the protons).
Nuclear Potential Nuclear Energy Levels There is extensive experimental evidence of the contrary hypothesis that the nucleons move in an effective potential well created by all the other nucleons. Since the nucleons are densely packed into a small region, it is expected that the chance of collision is very high. However, the interaction by collision is minimized by the Pauli exclusion principle, which forbids two fermions to occupy the same quantum state. If there are no nearby, unfilled quantum states that can be reached by the available energy for an interaction, then the interaction will not occur.

Figure 14-05a Nuclear Potential
[view large image]

Figure 14-05b Nuclear Energy Levels [view large image]

In the shell model, the potential well can be in the form of a square well or harmonic oscillator. A more realistic one is shown in Figure 14-05a with a round edge to avoid discontinuity and a Coulomb field for the charged protons. The energy levels obtained by solving the Schrodinger equation is shown on the left in Figure 14-05b. Including the spin-orbit interaction would split the levels by an amount depending on the orbital quantum number as shown in the middle of Figure 14-05b. The multiplicity of states (different possible orientations of angular momentum) is calculated by the formula 2j + 1, where j is the total angular momentum (orbit plus spin) quantum number designated as an subscript in the diagram. The "magic numbers" on the right suggests closed shell configuration, like the shells in atomic structure. They represent one line of reasoning which led to the development of a shell model for the nucleus. Other evidences include: The problem with the shell model is in the region of the rare-earth nuclei. The quadrupole moments predicted from the orbital motion of the individual protons are much smaller than those observed. From the shell model point of view, the rare-earth nuclei lie about midway between the neutron magic numbers 82 and 126. This is just the region for which shell model calculations are the most difficult since there are many particles outside a closed shell.

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Nuclear Decay

Unstable nuclei, called radioactive isotopes, will undergo nuclear decay to make it more stable. There are only certain types of nuclear decay which means that most isotopes can't jump directly from being unstable to being stable. It often takes several decays to eventually become a stable nucleus. When unstable nuclei decay, the reactions generally involve the emission of a particle and or energy. Half-lives are characteristic properties of the various unstable atomic nuclei and the particular way in which they decay. Alpha and beta decay are generally slower processes than gamma decay. Half-lives for beta decay range upward from 10-2 sec and, for alpha decay, upward from about 10-6 sec. Bismuth-209 has the longest half-life of 2x1019 years. Half-lives for gamma decay may be too short to measure (~ 10-14 second), though a wide range of half-lives for gamma emission has been reported.

Table 14-01 below summarizes the various types of nuclear decay with a few examples.

Type Emission Penetrating Power Example
Alpha Decay Helium nuclei 1, stopped by skin, very damaging due to ionization 92U238 => 90Th234 + 2He4
Applicable to nuclei with Z>83, see Figure 14-02
Beta Decay Electron, high speed 100, penetrates human tissue to ~ 1 cm 53I131 => 54Xe131 + -1e0
Applicable to nuclei with high neutron-proton ratio
Gamma Decay Photons, high energy 10000, highly penetrating but not very ionizing 92U238 => 90Th234 + 2He4 + 2 photon
Energy lost from settling within the nucleus after transmutation
Positron Emission Positron 100 6C11 => 5B11 + 1e0
Applicable to nuclei with a low neutron-proton ratio
Electron Capture Electron, inner shell Neutrino 37Rb81 + -1e0 => 36Kr81 + neutrino
Applicable to nuclei with a low neutron-proton ratio

Table 14-01 Types of Nuclear Decay

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Fission

Chain Reaction Nuclear Reactor If a massive nucleus like uranium-235 breaks apart (fission), then there will be a net yield of energy because the sum of the masses of the fragments will be less than the mass of the uranium nucleus. If the mass of the fragments is equal to or greater than that of iron at the peak of the binding energy curve,

Figure 14-11 Chain Reaction
[view large image]

Figure 14-12 Nuclear Reactor
[view large image]

(see Figure 14-01) then the products of the decay will be more tightly bound than they were in the uranium nucleus, and that decrease in mass comes off
in the form of energy according to the Einstein equation E = mc2. For elements lighter than iron fusion will yield energy.

In one of the most remarkable phenomena in nature, a neutron can be captured by a uranium-235 nucleus, rendering it unstable toward nuclear fission. When a U-235 nucleus splits, it gives off energy in the form of heat and Gamma radiation, which is the most powerful form of radioactivity and the most lethal. When this reaction occurs, the split nucleus will also give off two or three of its `spare' neutrons. These spare neutrons fly out to split other U-235 nuclei they come in contact with. In theory, it is necessary to split only one U-235 nucleus, and the neutrons from this will split other U-235 nuclei, which will split more...so on and so forth -- a chain reaction. (See Figure 14-11.) This progression does not take place arithmetically, but geometrically. All of this will happen within a millionth of a second. The minimum amount to start a chain reaction as described above is known as Critical Mass. The actual mass needed to facilitate this chain reaction depends upon the purity of the material and whether it is tampered. The tamper is a thick casing made of natural uranium. It reflected neutrons back into the core and helped to hold it together for a fraction of a second. For pure U-235, the bare critical mass is 50 kg and the tampered critical mass is 15 kg (with a spherical tamper size of 11.5 cm diameter); it is 10 kg and 5 kg respectively for Pu-239 (with 8 cm tamper size).

While uranium-235 is the naturally occurring fissionable isotope, there are other isotopes which can be induced to fission by neutron bombardment. Plutonium-239 is also fissionable, and both types have been used to make nuclear fission bombs. Plutonium-239 can be produced by breeding it from non-fissionable uranium-238 (by absorbing a neutron and then transmuted via the beta decay process). Spent fuel is taken out of the reactor after four years and can be recycled in a reprocessing plant. Some of the nuclear reactors at Hanford, Washington and the Savannah-River Plant, SC are designed for the production of bomb-grade plutonium-239. The other isotopes known to undergo fission upon neutron bombardment are listed in Table 14-02, which displays the critical (bare) mass, half-life, number of neutrons generated in spontaneous fission, and the rate of heat generation by radioactive decay. They all undergo transmutation via the alpha decay process. For comparison, the table also includes the two major fertile materials, Thorium-232 and Uranium-238, which in the presence of neutrons can produce the fissionable isotopes Uranium-233 and Plutonium-239, respectively.

Fissionable Isotope Crtiical Mass (kg) Half Life (years) Neutron Generation
(# / sec-kg)
Power Generation
(Watts / kg)
Protactinium-231 162 3.28x104 nil 1.3
Thorium-232 Infinite 1.41x1010 nil nil
Uranium-233 16.4 1.59x105 1.23 0.281
Uranium-235 47.9 7.0x108 0.364 6x10-5
Uranium-238 Infinite 4.5x109 0.11 8x10-6
Neptunium-237 59 2.14x106 0.139 0.021
Plutonium-238 10 88 2.67x106 560
Plutonium-239 10.2 2.41x104 21.8 2.0
Plutonium-240 36.8 6.54x103 1.03x106 7.0
Plutonium-241 12.9 14.7 49.3 6.4
Plutonium-242 89 3.76x105 1.73x106 0.12
Americium-241 57 433 1540 115
Americium-242 9 - 18 - - -
Americium-243 155 7.38x103 900 6.4
Curium-244 28 18.1 1.1x1010 2.8x103
Curium-245 13 8.5x103 1.47x105 5.7
Curium-246 84 4.7x103 9x109 10
Curium-247 7 1.55x107 - -
Berkelium-247 10 1.4x103 nil 36
Californium-251 9 898 nil 56

Table 14-02 Fissionable Isotopes

For efficient production of energy, the neutrons must be slowed down by moderation to increase their capture probability in fission reactors. Specifically, the initial fission of U-235 produces neutrons with energy of 2 Mev. Neutron with this energy has a fission probability about 1000 times less than a neutron with energy of 0.025 ev. So neutrons need to be slowed down, on average, by a factor of 100 million. A nuclear reactor uses heavy water (D2O) to slow down (moderate) the neutrons, while ordinary water (H2O) is used to minimize neutron loss (via the H2O + 2n => D2O reaction). The control rods used to regulate the rate of reaction are mainly composed of stainless steel tubes encapsulating silver-indium-cadmium (neutron) absorber material. A schematic diagram of a nuclear reactor is shown in Figure 14-12.

The incidents at Three Mile Island in 1979 and at Chernobyl in 1986 had slowed down the building of nuclear reactors. Currently, they generate 17% of the world's electricity. Global warming and rising energy needs has prompted a consortium of ten nations to plan the future reactor (~ 2035). The next generation reactors should be a lot cheaper to run, produce much less radioactive waste at accident-proof facilities, and perhaps eliminate reprocessing waste (into plutonium for assembling bombs). Unlike today's water-cooled reactors, which tend to run at about 300 oC, the new design will operate at temperatures from 510 oC to 1000 oC. This allows for more efficient conversion of heat to electricity. But these higher operating temperatures mean that the reactors will need new coolants. One of the most popular concepts is the supercritical-water-cooled reactor, which uses extreme pressures to prevent water from boiling at temperature up to 500 oC. The most advanced concept is helium gas cooling, which can achieve temperature in the range of 700 - 900 oC. Hydrogen can be split from water thermochemically at this temperature. The hydrogen gas can be used as fuel to convert into electricity for cars and homes. Operating at high temperatures also rules out conventional fuel systems in the form of metal rods as they melt at fairly low temperatures. Instead, the gas-cooled reactors will hold fuel pellets either in a honeycomb graphite structure, or fused into billiard-ball-sized graphite spheres, known as pebbles.

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Fusion

Fusion Reaction Hbomb Thermonuclear, or hydrogen bombs explode with enormous power via uncontrolled self-sustaining chain fusion reactions. Deuterium and tritium form helium under extremely high temperature, providing the energy:
D + T ==> He + n + 17.6 Mev (See Figure 14-13.)
In principle, a mixture of D and T heated to very high temperature and in high density will start a chain fusion

Figure 14-13 Fusion
[view large image]

Figure 14-14 Thermalnuclear
Explosion [view large image]

reaction, liberating an enormous amount of energy. But tritium is an unstable element; an ingenious method is to have it produced from lithium deuterate (Li6H2) in
the fission phase of the explosion -- thus one compound is used for both types of fuels (D and T). In a thermonuclear bomb, the explosive process begins with the detonation of what is called the primary stage. This consists of a relatively small quantity of conventional explosives, its detonation brings together enough fissionable uranium to create a fission chain reaction, which in turn produces another fission explosion inside the temper and raises the temperature to several million degrees. When the temperature of the mixture reaches 10,000,000 oK, fusion reactions take place. The neutrons from the fusion reactions induced fission in the uranium-238 pieces from the tamper and shield, which produced even more radiation and heat and the bomb exploded. (See Figure 14-14.)

Specialized type of small fusion bombs designed to release

neutrons rather than causing further fission reactions are called neutron bombs. This is accomplished by removing the U-238 tamper. Neutrons kill people, leaving the hardware and buildings intact. It is a "clean" bomb.

The theorized cobalt bomb is, on the contrary, a radioactively "dirty" bomb having a cobalt tamper. This tamper is made of cobalt-59, which is transmuted into cobalt-60 by neutrons released from the fusion reactions. Cobalt-60 has a half-life of 5.26 years and produces energetic (and thus penetrating) gamma rays. The half-life of Cobalt-60 is just long enough so that airborne particles will settle and coat the earth's surface before significant decay has occurred, thus making it impractical to hide in shelters. This is the "doomsday machine" since it is capable of wiping out life on earth.

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Effects of Nuclear Explosions

The detonation of a nuclear bomb over a target such as a populated city causes immense damage. The degree of damage depends upon the distance from the center of the bomb blast, its altitude, and the explosive energy.
Effects Hiroshima At the hypocenter (ground zero), everything is immediately vaporized by the high temperature (up to 300 million oC). Outward from the hypocenter, most casualties are caused by burns from the heat, injuries from the flying debris of buildings collapsed by the shock wave, and acute exposure to the high radiation. Beyond the immediate blast area, casualties are caused from the heat, radiation, and fires spawned from the heat wave. Figure 14-16 presents two views of Hiroshima before and after an atomic-bomb attack. It occurred in the morning (8:16 a.m.) of August 6, 1945.

Figure 14-15 Effects of A-Bomb [view large image]

Figure 14-16 Hiroshima
[view large image]

The bomb detonated at an altitude of 580 meters killing or wounding about half of its 350,000 inhabitants with long-term effects on incalculable numbers among the survivors.
In the long-term, radioactive fallout occurs over a wider area because of prevailing winds. The radioactive fallout particles enter the water supply and are inhaled and ingested by people at a distance from the blast. Radiation and radioactive fallout affect those cells in the body that actively divide (hair, intestine, bone marrow, reproductive organs). Radiation induced DNA damage would increase the risk of leukemia and cancer. A global nuclear warfare (many nuclear bombs exploding in different parts of the world) could produce a nuclear winter. In such scenario, the explosion of many bombs would raise great clouds of dust and radioactive material that would travel high into Earth's atmosphere. These clouds would block out sunlight. The reduced level of sunlight would lower the surface temperature of the planet and reduce photosynthesis by plants and bacteria. The reduction in photosynthesis would disrupt the food chain, causing mass extinction of life (including humans). This scenario is similar to the asteroid hypothesis that has been proposed to explain the extinction of the dinosaurs.

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